Why do transition metals and their compounds act as good catalysts?
d- and f-Block Elements
Original Khojo Papers practice question — not from a past board paper.
In a complex the five d orbitals are split into two sets of slightly different energy. An electron can absorb light of the right frequency and be promoted from the lower set to the higher, and the colour seen is the complement of the light absorbed. An ion with an empty or a completely filled d subshell has no such transition available and is colourless.
No citable source has been recorded for this record. Treat it as practice material, not as fact.
Zn2+ and Sc3+ compounds are colourless for exactly this reason.
From the same topic and chapter, at a similar level.
Why do transition metals and their compounds act as good catalysts?
d- and f-Block Elements
Why is Mn2+ more stable than Fe2+ towards oxidation?
d- and f-Block Elements
Why do transition elements show variable oxidation states?
d- and f-Block Elements
What is lanthanoid contraction and state two of its consequences.
d- and f-Block Elements
What is the van't Hoff factor, and what values does it take for sodium chloride and for acetic acid in benzene?
Solutions
Distinguish between Schottky and Frenkel defects and state the effect of each on density.
Solid State