Three organic compounds A, B and C are non cyclic functional isomers of
carbonyl compounds with molecular formula C4H8O. Isomers A and C give
positive Tollen’s test while compound B does not give positive Tollen’s test but
gives positive iodoform test. Compounds A and B on reduction with Zn amalgam
and conc. HCl give the same product.
(a) Write the structures of the compounds A, B and C.
(b) Out of the compounds A, B and C, which one will be the least reactive
towards addition of HCN.

(A) Fill in the blanks by choosing the appropriate word(s) from those given in the [4×1] brackets: [four, three, remains same, propane, ns1-2, increases, six, propan-2-ol, (n-1)d1-10, two, decreases, Clemmensen’s, Wolff-Kishner]
The molar conductance of a solution _________ on dilution but the
specific conductance of a solution _________ on dilution.

3] Identify the compounds [A], [B] and [C] in the following reactions. 6[H] HNO2 + HCl C6H5NH2
CH3CH2NH2 [A] [B] [C]
(2) P/Cl2 (2) H2O/H+ (2) Br2/KOH

What are reducing sugars? Give an example.
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3] Identify the compounds [A], [B] and [C] in the following reactions. 6[H] HNO2 + HCl C6H5NH2
C6H5NO2 [A] [B] [C]
Sn/HCl 273K-278K
(1) HNO2 (1) KCN (1) NH3/heat

(A) Fill in the blanks by choosing the appropriate word(s) from those given in the [4×1] brackets: [four, three, remains same, propane, ns1-2, increases, six, propan-2-ol, (n-1)d1-10, two, decreases, Clemmensen’s, Wolff-Kishner]
In the complex ion [CoCl(en)2ONO]+, the coordination number and
the oxidation number of the central metal ion are ______ and
________.

(A) Fill in the blanks by choosing the appropriate word(s) from those given in the [4×1] brackets: [four, three, remains same, propane, ns1-2, increases, six, propan-2-ol, (n-1)d1-10, two, decreases, Clemmensen’s, Wolff-Kishner]
Propanone on reaction with zinc amalgam in the presence of
concentrated HCl gives ______ and the reaction is called _______
reduction.