What is meant by an ambident nucleophile? Illustrate with the cyanide ion.
Haloalkanes and Haloarenes
Original Khojo Papers practice question — not from a past board paper.
The SN1 mechanism has two steps, the slow ionisation of the substrate to a carbocation followed by rapid attack by the nucleophile; its rate depends only on the substrate, and a racemic mixture is produced. The SN2 mechanism is a single step in which the nucleophile attacks as the leaving group departs; the rate depends on both reactants and the configuration is inverted.
No citable source has been recorded for this record. Treat it as practice material, not as fact.
Tertiary halides react mainly by SN1 and primary halides mainly by SN2.
From the same topic and chapter, at a similar level.
What is meant by an ambident nucleophile? Illustrate with the cyanide ion.
Haloalkanes and Haloarenes
Arrange the following in increasing order of reactivity towards SN1 and give the reason: 1-chlorobutane, 2-chlorobutane, 2-chloro-2-methylpropane.
Haloalkanes and Haloarenes
Why is chlorobenzene much less reactive towards nucleophilic substitution than chloroethane?
Haloalkanes and Haloarenes
Distinguish between Schottky and Frenkel defects and state the effect of each on density.
Solid State
What is the van't Hoff factor, and what values does it take for sodium chloride and for acetic acid in benzene?
Solutions
Name the four colligative properties and state what colligative means.
Solutions