(ii) Ammonia gas is passed over heated copper (II)
Rohit took two different salt solutions in test (D) H H H H
tubes C and D as shown in the figure below. He | | | |
added dilute HCl to each of the two test tubes. The H — C — C — C — C — H
products formed in the test tubes C and D are silver | | | |
chloride and lead chloride respectively. H H H H
(E) H H
| |
H— C—C—H
| |
dilute dilute H H
HCl HCl (F) H H H
| | |
H — C — C — C — H
| | |
Pb(NO3)2
AgNO3 H | H
solution solution H—C— H
Test Test |
State: H
(a) One common observation made by Rohit in (a) Which compound forms a single product with
both the reactions. bromine?
(b) The observations made by him on addition of (b) Which two compounds have the same molecular
excess of ammonium hydroxide to the products formula?
formed in: (c) Which two compounds will react together in the
1. test tube C present of concentrated H2SO4 to form a product
2. test tube D with a fruity smell?

Column A Column B a. N2 + 3H2  2NH3 1. Vanadium
Justify the following statements: (iv) Study the table given below. Use only the letters
(a) Anode is known as the oxidising electrode. given in the table to answer the questions. Do not
(b) Graphite electrodes are preferred in the identify the elements.
electrolysis of molten lead bromide. IA IIA IIIA IVA VA VIA VIIA 0

Column A Column B a. N2 + 3H2  2NH3 1. Vanadium
Give one significant observation when: (i) Given below are two sets of elements from two
(a) a solution of barium chloride is added to zinc different periods.
sulphate solution. Name the element with the highest ionisation
(b) lead nitrate is heated in a test tube. potential in each of the following sets.
(c) chlorine gas is passed over moist starch iodide (a) Al, Cl, Mg
paper. (b) Ne, O, F

Column A Column B a. N2 + 3H2  2NH3 1. Vanadium
A student was instructed by the teacher to prepare Pentoxide
and collect ammonia gas in the laboratory by
b. 4NH3 + 5O2 → 4NO + 2. Nickel
using aluminium nitride. The student had set up
6H2O
the apparatus as shown in the diagram below.
Study the given diagram and answer the following c. 2SO2 + O2  2SO3 3. Iron
questions: d. C2H4 + H2 → C2H6 4. Concentrated
X Ammonia gas Sulphuric acid
e. CuSO4.5H2O → CuSO4 5. Platinum
+ 5H2O
Y (v) (a) Draw the structural diagram for the following
Aluminium organic compounds:
nitride Water 1. 2-methyl propene 2. butanal
(b) Give IUPAC name for the following organic 3. H
compounds: |
1. Cl Cl H — C — H H H
| | | | |
H—C—C—H C=C — C — C — H
| | | | | |
Cl Cl H H H H
H H H
O
2. H C C C C
O—H
H H H
SECTION – B (40 Marks)
(Attempt any four questions from this Section)
Question-3 (iii) Name the gas produced during each of the following

Column A Column B a. N2 + 3H2  2NH3 1. Vanadium
The atomic number of two atoms 'X' and 'Y' are 14 reactions:
and 8 respectively: (a) When copper is treated with hot, concentrated
State nitric acid.
(a) the period to which 'X' belongs. (b) When ammonia is burnt in an atmosphere of
(b) the formula of the compound formed between oxygen.
'X' and 'Y'. (c) When ferrous sulphide reacts with dilute
(Do not identify X and Y) hydrochloric acid.

Column A Column B a. N2 + 3H2  2NH3 1. Vanadium
The reaction between concentrated sulphuric acid
E J Q
and magnesium can be represented by the equation
given below: L G
Mg + 2H2SO4 ® MgSO4 + 2H2O + SO2 M D P
If 60 g of magnesium is used in the reaction, N
calculate the following: (a) State the valency of element 'G'.
(a) The mass of sulphuric acid needed for the (b) Which element can exhibit catenation?
reaction. (c) Write the formula of the compound formed
(b) The volume of sulphur dioxide gas liberated at between 'M' and 'P'.
S.T.P.
[Atomic weight: Mg=24, H=1, S=32, O=16] Question 5

(ii) Ammonia gas is passed over heated copper (II)
A gas cylinder can hold 150 g of hydrogen under oxide in a combustion tube:
certain conditions of temperature and pressure. If (a) Name the gas evolved
an identical cylinder with the same capacity can (b) What will be the colour of the residue that is
hold 450 g of gas 'G' under the same conditions of left in the combustion tube at the end of the
temperature and pressure, find: reaction?
(a) the vapour density of the gas 'G'. (iii) Give balanced equations for the following:
(b) the molecular weight of gas 'G'. (a) Action of dilute hydrochloric acid on ammonium